I have used 64 bit version of Windows 7 to test the shortcuts, screenshots are included to give you a visual impression.
Firstly, use [Windows key] and [R] to invoke the run command box:

1) Character Map = charmap.exe
very useful for finding unusual characters.
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2) Color Management = colorcpl.exe
3) Device pairing wizard= devicepairingwizard.exe
4) Display Switch = displayswitch.exe
5) Direct X diagnostic = dxdiag.exe
5) DPI Scaling = dpiscaling.exe
8) Driver verification manager = verifier.exe (Undocumented, Security prompt will appear, accept it.)
7) Event Viewer Snapin Launcher = eventvwr.exe (Security prompt will appear, accept it.)
8 ) File siganture verification tool = sigverif.exe
9) Private character editor = eudcedit.exe (Security prompt will appear, accept it.)
allows creation or modification of characters :
10) IExpress Wizard = iexpress.exe
Create self-extracting / self-installing package:
11) Group policy editor = gpedit.msc
Used to manage group policies, and permissions, (Security prompt will appear, accept it.)
12) Language setup = lpksetup.exe
(Security prompt will appear, accept it.)
13) Magnifier = magnify.exe
14) Memory diagnostic tool = mdsched.exe
(Security prompt will appear, accept it.)
15) Microsoft Synchronization Manager = mobsync.exe
It works in Microsoft Windows XP too, undocumented for Microsoft Windows XP.
16) Microsoft remote assistance = msra.exe
17) Microsoft diagnostic troubleshooting wizard = msdt.exe
(Security prompt will appear, accept it.)
18) Microsoft Malicious Software removal tool = mrt.exe
19) Narrator = narrator.exe
20) Network shared folder wizard = shrpubw.exe
(Security prompt will appear, accept it.) Creates shared folders on network:
21) ODBC Data Source Administrator = odbcad32.exe
(Security prompt will appear, accept it.)
22) Problem steps recorder = psr.exe23) Registry editor = regedit.exe
24) File encryption certificate = rekeywiz.exe
25) Remote desktop = mstsc.exe
26) Remote connection manager = rasphone.exe
27) System restore = rstrui.exe
28) Services = services.msc
(Security prompt will appear, accept it.)
29) Sound Volume = sndvol.exe
30) Sound recorder = soundrecorder.exe
31) System activation = slui.exe
32) System monitor = perfmon.exe
very useful, highly configurable tool, tells you everything you ever wanted to know about any aspect of PC performance, for uber-geeks only.
33) Syskey = syskey.exe
Secures Windows 7 Account database – use with care, it’s virtually undocumented but it appears to encrypt all passwords, I’m not sure of the full implications.
34) System configuration = msconfig.exe
35) System information = msinfo32.exe
